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當(dāng)前位置:上海瑞齊生物科技有限公司>>公司動(dòng)態(tài)>>人造材料自修復(fù)方面的研究獲新進(jìn)展
模仿生物骨骼的自修復(fù)(self-healing)過(guò)程,研究人員在纖維增強(qiáng)的高分子復(fù)合材料中引入通道系統(tǒng),通過(guò)注入樹(shù)脂對(duì)材料損傷的部位進(jìn)行修復(fù)。經(jīng)過(guò)修復(fù)的復(fù)合材料的抗壓強(qiáng)度可以達(dá)到損傷之前的97%。
歐洲噴氣式戰(zhàn)斗機(jī)的機(jī)身主要是由纖維增強(qiáng)高分子復(fù)合材料構(gòu)成。這種材料較同等的金屬材料相比重量更輕,強(qiáng)度和硬度更高;但是塑性較差。纖維增強(qiáng)在本質(zhì)上是一個(gè)平面的機(jī)制,對(duì)于所受到的沖擊無(wú)法較好地吸收和釋放。而作為飛行器的面板來(lái)講,細(xì)微的沖擊損傷是非常難進(jìn)行檢測(cè)的,但卻對(duì)材料的機(jī)械性能有重要的影響。
來(lái)自布里斯托大學(xué)的Richard Trask博士及同事們?cè)噲D通過(guò)使材料具備自修復(fù)的能力來(lái)解決這一問(wèn)題。我們?nèi)梭w的骨骼也是由層狀的脆性單元所組成的復(fù)合材料。但是,當(dāng)骨骼中產(chǎn)生裂紋時(shí),它可以通過(guò)兩種骨細(xì)胞進(jìn)行重建:蝕骨細(xì)胞(osteoclasts)和成骨細(xì)胞(osteoblasts)。蝕骨細(xì)胞可以侵蝕骨頭,它們?cè)谒劳龅墓穷^中產(chǎn)生通道或者管道。血管通過(guò)這些管道將成骨細(xì)胞帶到損傷的位置,慢慢生成新的骨骼。
研究人員通過(guò)“溶模(lost wax)”的方法將一個(gè)管道系統(tǒng)引入到高分子復(fù)合材料中。如果材料發(fā)生了損傷,就可以將一種修復(fù)用的樹(shù)脂注入這些管道中,對(duì)損傷的部位進(jìn)行修復(fù)。實(shí)驗(yàn)發(fā)現(xiàn),經(jīng)過(guò)修復(fù)的復(fù)合材料的抗壓強(qiáng)度可以達(dá)到損傷之前的97%。
這項(xiàng)人造材料自修復(fù)方面的研究對(duì)相關(guān)工程領(lǐng)域的發(fā)展具有重要的意義。(生物谷 )
doi:10.1002/adfm.201101100
PMC:
PMID:
Self-Healing Fibre Reinforced Composites via a Bioinspired Vasculature
Christopher J. Norris, Gregory J. Meadway, Michael J. O'Sullivan, Ian P. Bond, Richard S. Trask
This paper demonstrates the first steps towards self-healing composites that exploit a design philosophy inspired by the damage tolerance and self-repair functions of bone. Cracking in either fibre reinforced polymers (FRP) or bone, if left unattended, can grow under subsequent cyclic stresses eventually leading to catastrophic failure of the structure. On detection of cracks, an FRP component must be repaired or compley replaced, whereas bone utilises a series of complex processes to repair such damage. Under normal circumstances, these processes allow the skeleton to continually perform over the lifespan of the organism, a highly desirable aspiration for engineering materials. A simple vasculature design incorporated into a FRP via a “lost wax” process was found to facilitate a self-healing function which resulted in an outstanding recovery (≥96%) in post-impact compression strength. The process involved infusion of a healing resin through the vascule channels. Resin egress from the backface damage, ultrasonic C-scan testing, and microscopic evaluation all provide evidence that sufficient vascule–damage connectivity exists to confer a reliable and efficient self-healing function.
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